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LH band edge will increase (with the inverted energy picture), hence the HH and LH bands cease to be degenerate, with the light-holes at the zone centre having an energy greater than that of the heavy-holes. In the opposite case with aiatt smaller than O,Q, the thin layer acquires a tensile in-plane strain, and the above effects are reversed. Returning to the 6 x 6 Hamiltonian, the eigenvalue equation is clearly a sixth-order polynomial in the energy E. It can be written as a square of a third-order polynomial, which can be solved analytically, but this is not an easy thing to do. Again, looking at the special case of k = 0 summarised in equation (10.26), notice that the diagonal elements Pe + Q stand alone in both their rows and columns, which means that this is a doubly degenerate eigenvalue and can be factored out. The remaining problem fourth-order polynomial is then easier to solve and in fact it can be seen that it is the square of a quadratic polynomial. The eigenenergies, which are the edges of the three valence bands in a strained semiconductor, follow as:
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The portion of the Pro t & Loss Statement re ecting income, cost of goods sold, and gross pro t for Larry s Landscaping is shown in Figure 4-2.
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It is important to note, for the purpose of a later discussion on the band offset at an interface between different materials, that the average ('centre of mass') of these three valence band edges shifts only because of the hydrostatic component Pe, from its unstrained value of Aso/3. In the case of a large spin orbit splitting (Aso Qe) by taking the first two terms in Taylor series expansions of the roots in equation (10.28) the results in equation (10.27) are recovered, while the SO band in this limit appears relatively insensitive to strain. Values of the parameters necessary for strain calculations in a few common semiconductors are given in Table 10.1. 10.7 HOLE SUBBANDS IN HETEROSTRUCTURES In a heterostructure, where the material composition is modulated, and hence all the material parameters, as well as the valence band edge energies become position dependent, the Hamiltonian in equation (10.2) has to be modified appropriately. For some time it has been accepted that equation (10.2) is modified in analogy with the effective mass Schrodinger equation: in a 2D system, for example, kx and ky remain as they are, because only a plane-wave type of solution is allowed in the non-quantising * directions, along which the potential is constant, however the wave vector kz along the quantising (growth) direction is substituted for its quantum mechanical operator id/dz, and then, in order to preserve the hermiticity of the Hamiltonian, the terms
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Figure 4-2: Gross pro t refers to the difference between cost of goods sold and the total income. QuickBooks refers to the process of including a transaction in an account, for the purpose of recalculating the account balance to re ect the transaction, as posting the transaction to the account.
Thus for the periodicity condition to be fulfilled, the second exponential term must be identical to 1, which implies that:
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